Re: [學科] 關於有機金屬 Organometalic定義
※ 引述《a1014210 (rainbow)》之銘言：
: 根據其定義為具有直接 金屬-有機配位基鍵結的化合物
: 這真的很攏統不適很明白阿?
: 難道只要有C接上金屬那就都屬於有機金屬嗎?
有機金屬的定義很廣 而且眾說紛紜
你問十個做有機金屬的老師可能都會給你十種答案
那就來看期刊"Organometallics"裡面給作者的指引吧
http://pubs.acs.org/paragonplus/submission/orgnd7/orgnd7_authguide.pdf
For the purposes of this journal, an "organometallic" compound will be defined
as one in which there is a bonding interaction (ionic or covalent, localized or
delocalized) between one or more carbon atoms of an organic group or molecule
and a main group, transition, lanthanide, or actinide metal atom (or atoms).
對這個期刊的目標而言，"有機金屬"化合物被定義為化合物裡有一個或多個碳與主族元素
.過渡元素.鑭系金屬.錒系金屬之間有鍵結作用力(離子或共價，定域化或離域化)
Following longstanding tradition, organic derivatives of the metalloids (boron,
silicon, germanium, arsenic, and tellurium) will be included in this definition.
遵循長久以來的傳統，類金屬(B.Si.Ge.As.Te)的有機衍生物皆在此定義裡。
Furthermore, manuscripts dealing with metal-containing compounds that do not
contain metal–carbon bonds will be considered if there is a close relationship
between the subject matter and the principles and practice of organometallic
chemistry.
更進一步，稿件裡的金屬化合物若不包含金屬-碳鍵，但擁有與有機金屬化學主旨與應用
緊密相關，也可以被列入考量。
Such compounds may include, inter alia, representatives from the following classes: molecular metal hydrides; metal alkoxides,
thiolates, amides, and phosphides; metal complexes containing organo-group 15
and 16 ligands; metal nitrosyls. Papers dealing with certain aspects of
organophosphorus, organoselenium, and organosulfur chemistry also will be
considered.
這些化合物的代表性例子包含了thiolates.amides和phosphides。包含15族.16族元素
ligands的金屬錯合物，一氧化氮錯合物。包括磷化物.硒化物.硫化物的化學文章也是
被列入考量的。
俊毅Bird Man
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