Re: [問題]想請問一題有機化學 謝謝

看板Chemistry作者 (林小方)時間16年前 (2009/05/20 21:12), 編輯推噓1(100)
留言1則, 1人參與, 最新討論串2/2 (看更多)
: A sample of 1-chloro-1-phenylethane with an [α]25D of -94.8° is reacted : with NH3 in methanol/water solvent. The major substitution product of the : reaction is 1-phenyl-1-ethylamine with an [α]25D of -8.6°. Given that : optically pure (R) 1-chloro-1-phenylethane has a specific rotation of -109.0° : and that optically pure (R) 1-phenyl-1-ethylamine has a specific rotation of : +39.3°, which of the following statements best describes this reaction? : A)Net inversion 12% with 88% racemization -- SN2 mechanism : B)Net inversion 12% with 88% racemization -- SN1 mechanism : C)Net inversion 25% with 75% racemization -- SN1 mechanism : D)Net inversion 75% with 25% racemization -- SN2 mechanism : E)Net inversion 88% with 12% racemization -- SN2 mechanism 請問應該怎麼算呢 謝謝 -- ※ 發信站: 批踢踢實業坊(ptt.cc) ◆ From: 59.127.168.123

05/20 21:34, , 1F
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05/20 21:34, 1F
文章代碼(AID): #1A507F5p (Chemistry)
文章代碼(AID): #1A507F5p (Chemistry)