Re: 請問一題關於熱力學的問題
※ 引述《GOPOL (爬不起來阿!!)》之銘言:
: in the plot of enthalpy VS temperature for metals A and B
: if the slope of A less than B which of the following is true
: (A)the entropy of A is less than B
: (B)melting point of metal A is higher than that of metal B
: (C)more heat is needed to heat up metal B than A when the equal
: moles of A and B are used
: (D)heat will flow from B to A when they are in direct contact
: 請化學高手指教一下 這一題不太懂
氣體
定容狀態
dU=TdS-PdV
dS=dU/T+ P/T dV
dS=Cv/T dT + R/V dV
因為題目是金屬
定壓
dH=TdS+VdP
dS=dH/T -V/TdP
dS=Cp/T dT-R/P dP
考慮斜率 H&T關係
dH/dT=CpdT/dT=Cp
--
※ 發信站: 批踢踢實業坊(ptt.cc)
◆ From: 203.67.78.143
推
02/09 14:17, , 1F
02/09 14:17, 1F
→
02/09 22:00, , 2F
02/09 22:00, 2F
推
02/10 00:18, , 3F
02/10 00:18, 3F
討論串 (同標題文章)
本文引述了以下文章的的內容:
完整討論串 (本文為第 2 之 2 篇):