[化學] 98b卷非選!!particle in abox!!

看板TransBioChem作者 (貝利亞)時間14年前 (2011/06/22 20:20), 編輯推噓2(205)
留言7則, 2人參與, 最新討論串1/1
For a paticle in a box of nanometer size, the energy level is quntized as deltaE =(2n+1)h^2/8ml^ Use this information to quantitatively explain the following observations. (b)Heavy particles have larger entropy than lighter paticles of the same size of box at the same temperature. 哪個高手拜託了!! -- ※ 發信站: 批踢踢實業坊(ptt.cc) ◆ From: 114.42.103.194

06/26 16:04, , 1F
(a)E(n)=n^2*h^2/8ml^2
06/26 16:04, 1F

06/26 16:06, , 2F
deltaE=E(n+1)-E(n)=[(n+1)^2-n^2]h^2/8ml^2=正解
06/26 16:06, 2F

06/26 16:08, , 3F
若要寫更完整則需推倒薛丁格方程式解出E(n)
06/26 16:08, 3F

06/26 19:59, , 4F
大一普化有教到薛丁格的推倒??
06/26 19:59, 4F

06/26 23:24, , 5F
普物有,普化只要記起來就可以了,化學要到大2物化才有
06/26 23:24, 5F

06/26 23:25, , 6F
教推導,但台大喜歡考超出大一範圍的東西0.0
06/26 23:25, 6F

06/28 20:42, , 7F
@_@ 怪不得有幾題總是得翻一翻學長課本才知道!
06/28 20:42, 7F
文章代碼(AID): #1E0TuRqq (TransBioChem)