[試題] 101上 陳昭岑 有機化學第一次小考
課程名稱︰有機化學
課程性質︰必修
課程教師︰陳昭岑
開課學院：工學院
開課系所︰化工系
考試日期（年月日）︰2012/12/25
考試時限（分鐘）：20mins
是否需發放獎勵金：是
（如未明確表示，則不予發放）
試題 :
1. Compound A has the formula C8H12and is optically active. It reacts with
hydrogen in the presence of platinum metal to give B, which has the formula
C8H18 and is optically inactive. Careful hydrogenation of A using Lindlar
catalyst (Pd/BaSO4/quinoline/S) gives C, which has the formula C8H14and is
optically active. Compound A reacts with sodium in ammonia to give D which
also has the formula C8H14 and is optically active. What is compound A?
圖http://ppt.cc/Kp9I
2. The reaction of isobutylene (CH3)2C=CH2 with methanol in the presence of
mercuric diacetate will give (A) tert-butyl methyl ether; (B) isobutyl methyl
ether; (C) tert-butyl acetate; (D) isobutyl acetate
3.Devise a sensible synthetic pathway to prepare 3-phenyl-3-pentanol
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